Organic Chemistry I/II - 2009-2010
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Organic Chemistry I/II - 2009-2010
Full chapter lectures and in-class recordings from Organic Chemistry I and II, at Anoka-Ramsey Community College in Coon Rapids, MN. Email andrew.aspaas@anokaramsey.edu from a .edu email address for access to the videos!
Recent Episodes
36 episodes
Ch 24: Amines and heterocycles
Nomenclature; properties and basicity of amines; synthesis; reductive amination; Hoffman elimination; Sandmeyer reaction; heterocycles; spectroscopy
Ch 23: Carbonyl condensation reactions
Aldol reaction; dehydration; mixed aldol; intramolecular aldol; Claisen reaction (mixed, intramolecular); Michael reaction; Stork enamine reaction; Ro...
Ch 22: Carbonyl alpha-substitution reactions
Keto-enol tautomerism; reactivity of enols; alpha-halogenation; enolate ion formation and reactivity; alkylation of enolate ions
Ch 21: Carboxylic acid derivatives
Naming; nucleophilic acyl substitution reactions; reactions of carboxylic acids; chemistry of acid halides, anhydrides, esters, amides; biological thi...
Ch 20a: Carboxylic acids
Carboxylic acid nomenclature; structure and properties; acidity; the Henderson-Hasselbalch equation; substituent effects on acidity; preparation; spec...
Ch 19: Aldehydes and ketones: nucleophilic addition reactions
Aldehyde and ketone nomenclature; preparation of aldehydes and ketones; oxidation;hydration; cyanohydrin formation; Grignard and hydride reactions; im...
Ch 18: Ethers and epoxides; thiols and sulfides
Ether nomenclature, synthesis, cleavage; epoxide synthesis and ring-opening; thiols and sulfides; spectroscopy of ethers
Ch 17: Alcohols and phenols
Nomenclature; acid-base properties; synthesis of alcohols from alkenes; reduction of carbonyl compounds; Grignard reaction; conversion of alcohols int...
Ch 16: Chemistry of benzene: electrophilic aromatic substitution
Bromination; other aromatic substitutions; alkylation of aromatic rings: the Friedel-Crafts reaction; substituent effects in aromatic rings; trisubsti...
Ch 15: Benzene and aromaticity
Aromatic compound nomenclature; benzene MOs; 4n+2 rule; aromatic ions; aromatic heterocycles; polycyclic aromatic compounds; spectroscopy of aromatic...
Ch 14: Conjugated compounds and UV spectroscopy
Conjugation, MOs, allylic carbocations, Diels-Alder reaction, UV spectroscopy
Ch 12: Mass spectrometry and infrared spectroscopy
MS theory; interpretation of mass spectra; IR theory, interpretation of IR spectra
Jan 12: Intro to 2062
Ch 13: Nuclear magnetic resonance spectroscopy
NMR absorptions; chemical shift; 13C NMR; 1H NMR; integration; spin-spin splitting
Ch 11: Substitution and elimination
SN2 reaction; SN1 reaction; elimination reactions and Zaitsev's rule; E2 reaction and cyclohexane conformation; E1 reaction; summary of reactivity; sy...
Ch 10: Organohalides
Nomenclature and structure of organohalides; radical halogenation; preparation of organohalides; Grignard and Gilman reagents
Ch 9: Stereochemistry
Chirality; enantiomers; assigning configuration; diastereomers; meso compounds; racemic mixtures; stereochemistry of reactions
Ch 8: Alkynes: an intro to organic synthesis
Nomenclature; preparation of alkynes; addition of HX and X2; hydration and tautomerism; reduction; formation and alkylation of acetylide ions
Ch 7: Alkenes: reactions and synthesis
Preparation of alkenes; addition of halogens; halohydrin formation; oxymercuration; hydroboration; cyclopropane synthesis; hydrogenation; epoxidation...
Ch 6: Alkenes: structure and reactivity
Degree of unsaturation; alkene nomenclature; cis-trans and E-Z isomerism; electrophilic addition; Markovnikov's rule; carbocation structure and stabil...